Thallium-201 - Biblioteka.sk

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Thallium-201
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Isotopes of thallium (81Tl)
Main isotopes[1] Decay
abun­dance half-life (t1/2) mode pro­duct
201Tl synth 3.0421 d ε 201Hg
203Tl 29.5% stable
204Tl synth 3.78 y β 204Pb
ε + β+ 204Hg
205Tl 70.5% stable
Standard atomic weight Ar°(Tl)

Thallium (81Tl) has 41 isotopes with atomic masses that range from 176 to 216. 203Tl and 205Tl are the only stable isotopes and 204Tl is the most stable radioisotope with a half-life of 3.78 years. 207Tl, with a half-life of 4.77 minutes, has the longest half-life of naturally occurring Tl radioisotopes. All isotopes of thallium are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed.

Thallium-202 (half-life 12.23 days) can be made in a cyclotron[4] while thallium-204 (half-life 3.78 years) is made by the neutron activation of stable thallium in a nuclear reactor.[5]

In the fully ionized state, the isotope 205Tl becomes beta-radioactive, decaying to 205Pb,[6] but 203Tl remains stable.

205Tl is the decay product of bismuth-209, an isotope that was once thought to be stable but is now known to undergo alpha decay with an extremely long half-life of 2.01×1019 y.[7] 205Tl is at the end of the neptunium series decay chain.

The neptunium series decay chain, which ends at 205Tl.

List of isotopes

Nuclide[8]
[n 1]
Historic
name
Z N Isotopic mass (Da)[9]
[n 2][n 3]
Half-life
[n 4]
Decay
mode

[n 5]
Daughter
isotope

[n 6]
Spin and
parity
[n 7][n 4]
Natural abundance (mole fraction)
Excitation energy[n 4] Normal proportion Range of variation
176Tl[10] 81 95 176.00059(21)# 2.4+1.6
−0.7
 ms
p (~63%) 175Hg (3−, 4−, 5−)
α (~37%) 172Au
176mTl ~671 keV 290+200
−80
 μs
p (~50%) 175Hg
α (~50%) 172mAu
177Tl[11] 81 96 176.996427(27) 18(5) ms α (73%) 173Au (1/2+)
p (27%) 176Hg
177mTl 807(18) keV 230(40) μs p (51%) 176Hg (11/2−)
α (49%) 173Au
178Tl[12] 81 97 177.99490(12)# 255(9) ms α (62%) 174Au (4-,5-)
β+ (38%) 178Hg
β+, SF (0.15%) (various)
179Tl[13] 81 98 178.99109(5) 437(9) ms α (60%) 175Au (1/2+)
β+ (40%) 179Hg
179m1Tl 825(10)# keV 1.41(2) ms α 175Au (11/2−)
IT (rare) 179Tl
β+ (rare) 179Hg
179m2Tl 904.5(9) keV 119(14) ns IT 179Tl (9/2−)
180Tl[14] 81 99 179.98991(13)# 1.09(1) s β+ (93%) 180Hg 4-#
α (7%) 176Au
β+, SF (0.0032%) 100Ru, 80Kr[15]
181Tl[16] 81 100 180.986257(10) 2.9(1) s β+ (91.4%) 181Hg 1/2+#
α (8.6%) 177Au
181mTl 834.9(4) keV 1.40(3) ms IT (99.60%) 181Tl (9/2−)
α (0.40%) 177Au
182Tl 81 101 181.98567(8) 2.0(3) s β+ (96%) 182Hg 2−#
α (4%) 178Au
182m1Tl 100(100)# keV 2.9(5) s α 178Au (7+)
β+ (rare) 182Hg
182m2Tl 600(140)# keV 10−
183Tl 81 102 182.982193(10) 6.9(7) s β+ (98%) 183Hg 1/2+#
α (2%) 179Au
183m1Tl 630(17) keV 53.3(3) ms IT (99.99%) 183Tl 9/2−#
α (.01%) 179Au
183m2Tl 976.8(3) keV 1.48(10) μs (13/2+)
184Tl 81 103 183.98187(5) 9.7(6) s β+ 184Hg 2−#
184m1Tl 100(100)# keV 10# s β+ (97.9%) 184Hg 7+#
α (2.1%) 180Au
184m2Tl 500(140)# keV 47.1 ms IT (99.911%) (10−)
α (.089%) 180Au
185Tl 81 104 184.97879(6) 19.5(5) s α 181Au 1/2+#
β+ 185Hg
185mTl 452.8(20) keV 1.93(8) s IT (99.99%) 185Tl 9/2−#
α (.01%) 181Au
β+ 185Hg
186Tl 81 105 185.97833(20) 40# s β+ 186Hg (2−)
α (.006%) 182Au
186m1Tl 320(180) keV 27.5(10) s β+ 186Hg (7+)
186m2Tl 690(180) keV 2.9(2) s (10−)
187Tl 81 106 186.975906(9) ~51 s β+ 187Hg (1/2+)
α (rare) 183Au
187mTl 335(3) keV 15.60(12) s α 183Au (9/2−)
IT 187Tl
β+ 187Hg
188Tl 81 107 187.97601(4) 71(2) s β+ 188Hg (2−)
188m1Tl 40(30) keV 71(1) s β+ 188Hg (7+)
188m2Tl 310(30) keV 41(4) ms (9−) Zdroj:https://en.wikipedia.org?pojem=Thallium-201
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